毛細管柱測定化妝品中新鈴蘭醛
毛細管柱測定化妝品中新鈴蘭醛 詳細信息:
名稱:毛細管柱
固定相:50%-苯基-甲基聚硅氧烷
規(guī)格:30 m×0.25 mm(內(nèi)徑)×0.25 μm
型號:HH-17MS
應(yīng)用:GB/T 40891-2021 化妝品中新鈴蘭醛的測定 氣相色譜-質(zhì)譜法
據(jù)統(tǒng)計,化妝品過敏中少有35%是由香料引起的過敏。針對可能由于使用香料所引發(fā)的問題,各主要相關(guān)國際機構(gòu)與組織出臺了相應(yīng)的法規(guī)政策以對香料香精市場進行約束。香精香料直接或間接地與“人體健康”相關(guān)聯(lián),成為各國政府強制管理的對象。歐盟化妝品法規(guī)(ecno.1223/2009-eucosmeticsregulation-inforce)根據(jù)醫(yī)院相關(guān)過敏數(shù)據(jù)的統(tǒng)計結(jié)果規(guī)定:符合“在不可沖洗型化妝品中含量大于等于0.001%;在可沖洗型化妝品中含量大于等于0.01%”條件時,化妝品香料中26種致敏原物質(zhì)必須在標(biāo)簽上標(biāo)注(在歐盟發(fā)布的化妝品指令2005年修訂前規(guī)定香料成分免于標(biāo)簽標(biāo)注,僅以“香料或香精”標(biāo)出即可),借此來提示對此類物質(zhì)過敏人群購買時應(yīng)謹(jǐn)慎。
新鈴蘭醛是一種香氣不同尋常、價值極高的含氧萜烯類合成香料,它具有持久的鈴蘭花香香韻和清淡而甜潤的兔耳草花香氣,并有豐富的余香,香氣溫和而穩(wěn)定,其柔和的花香似羥基香茅醛,但強度更大。由于新鈴蘭醛在香精配方中的作用顯著,越來越受到重視,已經(jīng)在香水香精等各種香精中逐漸取代了傳統(tǒng)的鈴蘭花香型合成香料鈴蘭醛的位置。
新鈴蘭醛,英文名稱為lyral,為對(間)-(4-羥基-4-甲基戊基)-3-環(huán)己烯-1-甲醛同分異構(gòu)體的混合物,分子式為c12h22o2,分子量為210.32,化學(xué)結(jié)構(gòu)式為式(i)和式(ii),亦可分別稱為新鈴蘭醛i和新鈴蘭醛ii或者新鈴蘭醛1和新鈴蘭醛2。新鈴蘭醛是一種重要的精細化學(xué)品,為無色粘性液體,具有清淡而甜潤的兔耳草花香,有較好的鈴蘭香韻,香氣穩(wěn)定而持久。新鈴蘭醛在日化香精中應(yīng)用廣泛,可用于配制香水、香皂、洗滌劑、化妝品等日化產(chǎn)品的香精。
浩瀚色譜(山東)應(yīng)用技術(shù)開發(fā)有限公司,研發(fā)化妝品中新鈴蘭醛的測定 氣相色譜-質(zhì)譜法,HH-17MS毛細管柱,外標(biāo)法定量,結(jié)果滿意。
毛細管柱測定化妝品中新鈴蘭醛 測試譜圖:




Determination of Lilyaldehyde in Cosmetics by Capillary Column
Determination of Lily of the Valley Aldehyde in Cosmetics by Capillary Column Details:
Name: capillary column
Statio
nary Phase: 50%-Phenyl-Methylpolysiloxane
Specifications: 30 m × 0.25 mm (inner diameter) × 0.25 μm
Model: HH-17MS
Application: GB/T 40891-2021 Determination of Lilylaldehyde in Cosmetics-Gas Chromatography-Mass Spectrometry
According to statistics, at least 35% of cosmetic allergies are caused by fragrance allergies. In respo
nse to the problems that may be caused by the use of fragrances, major relevant internatio
nal institutions and organizations have issued correspo
nding regulations and policies to restrict the fragrance and essence market. Flavor and fragrance are directly or indirectly related to "human health" and become the object of compulsory management by governments of various countries. The European Unio
n Cosmetics Regulation (ecno.1223/2009-eucosmeticsregulation-inforce) stipulates that according to the statistical results of hospital-related allergy da
ta: it is in line with "the co
ntent of non-flushable cosmetics is greater than or equal to 0.001%; the co
ntent of flushable cosmetics is greater than or equal to 0.01%" 26 kinds of allergens in cosmetic fragrances must be marked on the label (before the revision of the Cosmetic Directive issued by the European Unio
n in 2005, it was stipulated that fragrance ingredients were exempted from labelling, and o
nly marked as "fragrance or essence"). This suggests that people who are allergic to such substances should be cautious when purchasing.
New lily of the valley aldehyde is a kind of oxygen-co
ntaining terpene synthetic fragrance with unusual aroma and high value. It has a long-lasting lily-of-the-valley fragrance and a light and sweet rabbit ear flower fragrance, and has a rich aftertaste, aroma Mild and stable, its soft floral scent is like Hydroxycitronellal, but more intense. Due to the significant role of new lily of the valley aldehyde in flavor formulations, it has been paid more and more attention, and has gradually replaced the traditio
nal lily-of-the-valley flower-flavored synthetic fragrance lily of the valley aldehyde in various flavors such as perfume essence.
New lily of the valley aldehyde, the English name is lyral, is a mixture of p-(m)-(4-hydroxy-4-methylpentyl)-3-cyclohexene-1-carbaldehyde isomers, the molecular formula is c12h22o2, The molecular weight is 210.32, and the chemical structural formulas are formula (i) and formula (ii), which can also be called new lily aldehyde i and new lily aldehyde ii or new lily aldehyde 1 and new lily aldehyde 2, respectively. New lily of the valley aldehyde is an im
portant fine chemical. It is a colorless viscous liquid with a light and sweet fragrance of rabbit's ear grass. New lily of the valley aldehyde is widely used in daily chemical essence, and can be used to formulate the essence of daily chemical products such as high-end perfume, soap, detergent, cosmetics and so on.
Haohan Chromatography (Shandong) Application Technology Development Co., Ltd. developed the determination of new lily of the valley aldehyde in cosmetics by gas chromatography-mass spectrometry, HH-17MS capillary column, and quantitative external standard method, and the results were satisfactory.
Determination of Lily of the Valley Aldehyde in Cosmetics by Capillary Column Test Spectrum:
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